150-46-9
- Product Name：Triethyl borate-11B
- Molecular Formula：C6H15BO3
- Purity：99%
- Molecular Weight：145.994
Product Details;
CasNo： 150-46-9
Molecular Formula： C6H15BO3
Appearance： clear colourless liquid
Buy high quality and low price Triethyl borate-11B 150-46-9 now
- Molecular Formula:C6H15BO3
- Molecular Weight:145.994
- Appearance/Colour:clear colourless liquid
- Melting Point:-84.5 °C
- Refractive Index:n20/D 1.374(lit.)
- Boiling Point:120 °C at 760 mmHg
- Flash Point:11.1 °C
- PSA：27.69000
- Density:0.865 g/cm3
- LogP:1.08080
Triethyl borate(Cas 150-46-9) Usage
|
Preparation |
Triethyl borate can be prepared by adding anhydrous ethanol with boric acid or boron trioxide. Can be purified via distillation. |
|
Hazard |
Flammable, dangerous fire risk. |
|
Safety Profile |
Moderately toxic by ingestion. Aneye irritant. A very dangerous fire hazard when exposed toheat or flame. When heated to decomposition it emitsacrid smoke and irritating fumes. |
|
Purification Methods |
Dry it over sodium, then distil it. Also fractionate it through a gauze packed column. [Charnlet et al. J Chem Soc 2288 1952, as for tributyl borate Johnson & Tompkins Org Synth Coll Vol II 106 1943, Beilstein 1 III 1339, 1 IV 1365.] |
|
Definition |
ChEBI: A member of the class of borate esters obtained by the formal condensation of three equivalents of ethanol with boric acid. |
InChI:InChI=1/C17H20N2O2S.B/c1-3-20-15-9-5-13(6-10-15)18-17(22)19-14-7-11-16(12-8-14)21-4-2;/h5-12H,3-4H2,1-2H3,(H2,18,19,22);/q;+3
150-46-9 Relevant articles
-
Mikhailov,B.M.,Blokhina,A.N.
, (1962)
-
-
Brown et al.
, p. 3613 (1956)
-
-
Lehmann et al.
, p. 1226,1227,1228 (1959)
-
-
Tuchagues,Laurent
, p. 1469,1470,1471 (1974)
-
Application of Mechanochemical Catalysis to the Synthesis of Boric Acid Esters
Molchanov,Goidin,Golovin,Zolotovskaya,Bogdanov,Volodin
, p. 536 - 541 (2002)
The syntheses of triisopropyl borate and...
Reaction of triethyl phosphite with boron tribromide
Lewkowski, Jaroslaw,Mortier, Jacques,Vaultier, Michel
, p. 707 - 710 (2000)
Reaction of boron tribromide with trieth...
Methyl camouflage in the ten-vertex: Closo -dicarbaborane(10) series. Isolation of closo -1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues
Bakardjiev, Mario,Tok, Oleg L.,R??i?ka, Ale?,R??i?ková, Zdeňka,Holub, Josef,Hnyk, Drahomír,?palt, Zbyněk,Fanfrlík, Jind?ich,?tíbr, Bohumil
, p. 11070 - 11076 (2018)
Reported are procedures leading to the f...
Low-Temperature Hypergolic Ignition of 1-Octene with Low Ignition Delay Time
Sheng, Haoqiang,Huang, Xiaobin,Chen, Zhijia,Zhao, Zhengchuang,Liu, Hong
, p. 423 - 434 (2021/02/05)
The attainment of the efficient ignition...
Carboranes as Aryl Mimetics in Catalysis: A Highly Active Zwitterionic NHC-Precatalyst
Selg, Christoph,Neumann, Wilma,L?nnecke, Peter,Hey-Hawkins, Evamarie,Zeitler, Kirsten
supporting information, p. 7932 - 7937 (2017/06/19)
Modern catalysis takes advantage of aryl...
Rehydrogenation of aminoboranes to amine-boranes using H2O: Reaction scope and mechanism
Leitao, Erin M.,Manners, Ian
, p. 2199 - 2205 (2015/05/13)
Water has been successfully employed as ...
150-46-9 Process route
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20693-69-0
2,4-dicarba-closo-heptaborane
-
-
150-46-9
triethyl borate
-
-
1333-74-0
hydrogen
-
-
11113-50-1,14635-83-7
boric acid
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride;
20 h at 50°C then water-free HCl;
|
|
|
With
HCl;
20 h at 50°C then water-free HCl;
|
-
-
64-17-5
ethanol
-
-
878809-28-0
tris(2-tolyl)phosphane-borane(1:1)
-
-
150-46-9
triethyl borate
-
-
6163-58-2
tris-(o-tolyl)phosphine
| Conditions | Yield |
|---|---|
|
Inert atmosphere;
Reflux;
|
96% |
150-46-9 Upstream products
-
121-43-7
Trimethyl borate
-
64-17-5
ethanol
-
688-74-4
boric acid tributyl ester
-
23561-28-6
diethyl boronate
150-46-9 Downstream products
-
540-67-0
ethyl methyl ether
-
52386-21-7
2-ethoxy-4,4,6-trimethyl-1,3,2-dioxaborinane
-
4396-02-5
boric acid triisopentyl ester
-
593-90-8
trimethylborane
Relevant Products
-
-
Boron Trifluoride DihydrateCAS：13319-75-0
-
Boron tribromide-11BCAS：10294-33-4
